The atmosphere of Earth is a layer of gases Gas is one of four classical states of matter. Near absolute zero, a substance exists as a solid. As heat is added to this substance it melts into a liquid at its melting point , boils into a gas at its boiling point, and if heated high enough would enter a plasma state in which the electrons are so energized that they leave their parent atoms surrounding the planet Earth Earth is the third planet from the Sun, and the densest and fifth-largest of the eight planets in the Solar System. It is also the largest of the Solar System's four terrestrial planets. It is sometimes referred to as the World, the Blue Planet,[note 6] or by its Latin name, Terra.[note 7] that is retained by Earth's gravity Gravitation, or gravity, is one of the four fundamental interactions of nature , in which objects with mass attract one another. In everyday life, gravitation is most familiar as the agent that gives weight to objects with mass and causes them to fall to the ground when dropped. Gravitation causes dispersed matter to coalesce, thus accounting for. The atmosphere An atmosphere is a layer of gases that may surround a material body of sufficient mass,and that is held in place by the gravity of the body. An atmosphere may be retained for a longer duration, if the gravity is high and the atmosphere's temperature is low. Some planets consist mainly of various gases, but only their outer layer is their protects life on Earth In biology, an organism is any contiguous living system . In at least some form, all organisms are capable of response to stimuli, reproduction, growth and development, and maintenance of homoeostasis as a stable whole. An organism may either be unicellular (single-celled) or be composed of, as in humans, many trillions of cells grouped into by absorbing ultraviolet Ultraviolet light is electromagnetic radiation with a wavelength shorter than that of visible light, but longer than x-rays, in the range 10 nm to 400 nm, and energies from 3eV to 124 eV. It is so named because the spectrum consists of electromagnetic waves with frequencies higher than those that humans identify as the colour violet solar radiation Sunlight, in the broad sense, is the total frequency spectrum of electromagnetic radiation given off by the Sun. On Earth, sunlight is filtered through the Earth's atmosphere, and solar radiation is obvious as daylight when the Sun is above the horizon, warming the surface through heat retention (greenhouse effect The greenhouse effect is a process by which radiative energy leaving a planetary surface is absorbed by some atmospheric gases, called greenhouse gases. They transfer this energy to other components of the atmosphere, and it is re-radiated in all directions, including back down towards the surface. This transfers energy to the surface and lower), and reducing temperature Historically, two equivalent concepts of temperature have developed, the thermodynamic description and a microscopic explanation based on statistical physics. Since thermodynamics deals entirely with macroscopic measurements, the thermodynamic definition of temperature, first stated by Lord Kelvin, is stated entirely in empirical, measurable extremes between day On Earth, daytime is roughly the period on any given point of the planet's surface during which it experiences natural illumination from indirect or direct sunlight and night Night or nighttime is the period of time when the sun is below the horizon. The opposite of night is day . The start and end times of night vary based on factors such as season, latitude, longitude and timezone. Dry air contains roughly (by volume) 78.09% nitrogen Nitrogen is a chemical element that has the symbol N, atomic number of 7 and atomic mass 14.00674 u. Elemental nitrogen is a colorless, odorless, tasteless and mostly inert diatomic gas at standard conditions, constituting 78.08% by volume of Earth's atmosphere, 20.95% oxygen Oxygen (pronounced /ˈɒksɨdʒɨn/, OK-si-jin, from the Greek roots ὀξύς (acid, literally "sharp", from the taste of acids) and -γενής (-genēs) (producer, literally begetter), is the element with atomic number 8 and represented by the symbol O. It is a member of the chalcogen group on the periodic table, and is a highly, 0.93% argon Argon is a chemical element represented by the symbol Ar. Argon has atomic number 18 and is the third element in group 18 of the periodic table (noble gases). Argon is the third most common gas in the Earth's atmosphere, at 0.93%, making it more common than carbon dioxide. The complete octet (eight electrons) in the outer atomic shell makes it, 0.039% carbon dioxide Carbon dioxide forms approximately 0.04% of the nominal 5,000,000 gigatonnes of gas and aerosols that comprise the Earth's atmosphere. It is essential to photosynthesis in plants and other photoautotrophs, and is also a prominent greenhouse gas, and small amounts of other gases. Air also contains a variable amount of water vapor Water vapor or water vapour , also aqueous vapor, is the gas phase of water. Water vapor is one state of water within the hydrosphere. Water vapor can be produced from the evaporation of boiling liquid water or from the sublimation of ice. Under typical atmospheric conditions, water vapor is continuously generated by evaporation and removed by, on average around 1%.

The atmosphere has a mass of about 5 × 1018 kg, three quarters of which is within about 11 km (6.8 mi; 36,000 ft) of the surface. The atmosphere becomes thinner and thinner with increasing altitude, with no definite boundary between the atmosphere and outer space Outer space is the void that exists beyond any celestial body including the Earth. It is not completely empty (i.e. a perfect vacuum), but contains a low density of particles, predominantly hydrogen plasma, as well as electromagnetic radiation, magnetic fields, and neutrinos. Theoretically, it also contains dark matter and dark energy. An altitude of 120 km (75 mi) is where atmospheric effects become noticeable during atmospheric reentry Atmospheric reentry is the movement of human-made or natural objects as they enter the atmosphere of a planet from outer space, in the case of Earth from an altitude above the Kármán Line, . This article primarily addresses the process of controlled reentry of vehicles which are intended to reach the planetary surface intact, but the topic also of spacecraft. The Kármán line The Kármán line lies at an altitude of 100 km above the Earth's sea level, and is commonly used to define the boundary between the Earth's atmosphere and outer space. This definition is accepted by the Fédération Aéronautique Internationale (FAI), which is an international standard setting and record-keeping body for aeronautics and, at 100 km (62 mi), also is often regarded as the boundary between atmosphere and outer space.

Contents

Composition

Main article: Atmospheric chemistry Atmospheric chemistry is a branch of atmospheric science in which the chemistry of the Earth's atmosphere and that of other planets is studied. It is a multidisciplinary field of research and draws on environmental chemistry, physics, meteorology, computer modeling, oceanography, geology and volcanology and other disciplines. Research is Composition of Earth's atmosphere. The lower pie represents the trace gases which together compose 0.039% of the atmosphere. Values normalized for illustration. The numbers are from a variety of years (mainly 1987, with CO2 and methane from 2009) and do not represent any single source. Mean atmospheric water vapor

Air is mainly composed of nitrogen, oxygen, and argon, which together constitute the major gases of the atmosphere. The remaining gases are often referred to as trace gases,[1] among which are the greenhouse gases Greenhouse gases are gases in an atmosphere that absorb and emit radiation within the thermal infrared range. This process is the fundamental cause of the greenhouse effect. The main greenhouse gases in the Earth's atmosphere are water vapor, carbon dioxide, methane, nitrous oxide, and ozone. In our solar system, the atmospheres of Venus, Mars and such as water vapor, carbon dioxide, methane, nitrous oxide, and ozone. Filtered air includes trace amounts of many other chemical compounds A chemical compound is a pure chemical substance consisting of two or more different chemical elements that can be separated into simpler substances by chemical reactions. Chemical compounds have a unique and defined chemical structure; they consist of a fixed ratio of atoms that are held together in a defined spatial arrangement by chemical bonds. Many natural substances may be present in tiny amounts in an unfiltered air sample, including dust Dust is a general name for solid particles with diameters less than 20 thou . Particles in the atmosphere arise from various sources such as soil dust lifted up by wind, volcanic eruptions, and pollution. Dust in homes, offices, and other human environments contains small amounts of plant pollen, human and animal hairs, textile fibers, paper, pollen Pollen is a fine to coarse powder containing the microgametophytes of seed plants, which produce the male gametes . Pollen grains have a hard coat that protects the sperm cells during the process of their movement between the stamens to the pistil of flowering plants or from the male cone to the female cone of coniferous plants. When pollen lands and spores In biology, a spore is a reproductive structure that is adapted for dispersal and surviving for extended periods of time in unfavorable conditions. Spores form part of the life cycles of many bacteria, plants, algae, fungi and some protozoans. A chief difference between spores and seeds as dispersal units is that spores have very little stored, sea spray As a result, salt spray contains a high concentration of mineral salts, particularly chloride anions, and volcanic ash Volcanic ash consists of small tephra, which are bits of pulverized rock and glass created by volcanic eruptions, less than 2 millimetres in diameter. There are three mechanisms of volcanic ash formation: gas release under decompression causing magmatic eruptions; thermal contraction from chilling on contact with water causing phreatomagmatic. Various industrial pollutants Three factors determine the severity of a pollutant: its chemical nature, its concentration and its persistence. Some pollutants are biodegradable and therefore will not persist in the environment in the long term. However the degradation products of some pollutants are themselves polluting such as the products DDE and DDD produced from also may be present, such as chlorine Chlorine (pronounced /ˈklɔriːn/ KLOR-een, from the Greek word 'χλωρóς' (khlôros, meaning 'pale green'), is the chemical element with atomic number 17 and symbol Cl. It is a halogen, found in the periodic table in group 17 (formerly VII, VIIa, or VIIb). As the chloride ion, which is part of common salt and other compounds, it is abundant (elementary or in compounds), fluorine Fluorine is the chemical element with atomic number 9, represented by the symbol F. Fluorine forms a single bond with itself in elemental form, resulting in the diatomic F2 molecule. F2 (fluorine) is a supremely reactive, poisonous, pale, yellowish brown gas. Elemental fluorine is the most chemically reactive and electronegative of all the compounds, elemental mercury Mercury , also quicksilver (/ˈkwɪksɪlvər/) or hydrargyrum (/haɪˈdrɑrdʒɨrəm/ hye-DRAR-ji-rəm), is a chemical element with the symbol Hg (Latinized Greek: hydrargyrum, from "hydr-" meaning watery or runny and "argyros" meaning silver) and atomic number 80. A heavy, silvery d-block metal, mercury is one of six chemical, and sulfur Sulfur or sulphur is the chemical element that has the atomic number 16. It is denoted with the symbol S. It is an abundant, multivalent non-metal. Sulfur, in its native form, is a bright yellow crystalline solid. In nature, it can be found as the pure element and as sulfide and sulfate minerals. It is an essential element for life and is found in compounds such as sulfur dioxide Sulfur dioxide is the chemical compound with the formula SO2. It is produced by volcanoes and in various industrial processes. Since coal and petroleum often contain sulfur compounds, their combustion generates sulfur dioxide. Further oxidation of SO2, usually in the presence of a catalyst such as NO2, forms H2SO4, and thus acid rain. This is one [SO2].

Composition of dry atmosphere, by volume[2]
ppmv: parts per million Parts-per notation is used, especially in science and engineering, to denote relative proportions in measured quantities; particularly in low-value proportions at the parts-per-million (ppm) 10–6, parts-per-billion (ppb) 10–9, and parts-per-trillion (ppt) 10–12 level. Since parts-per notations are quantity-per-quantity measures, they are by volume (note: volume fraction Volume fractions φi are useful alternatives to mole fractions xi when dealing with mixtures in which there is a large disparity between the sizes of the various kinds of molecules; e.g., polymer solutions. They provide a more appropriate way to express the relative amounts of the various components is equal to mole fraction In chemistry, mole fraction x is a way of expressing the composition of a mixture. The mole fraction of each component i is defined as its amount of substance ni divided by the total amount of substance in the system, n for ideal gas only, see Gas Volume The volume of gas increases proportionally to absolute temperature and decreases inversely proportionally to pressure, approximately according to the ideal gas law:)
Gas Volume
Nitrogen Nitrogen is a chemical element that has the symbol N, atomic number of 7 and atomic mass 14.00674 u. Elemental nitrogen is a colorless, odorless, tasteless and mostly inert diatomic gas at standard conditions, constituting 78.08% by volume of Earth's atmosphere (N2) 780,840 ppmv (78.084%)
Oxygen Oxygen (pronounced /ˈɒksɨdʒɨn/, OK-si-jin, from the Greek roots ὀξύς (acid, literally "sharp", from the taste of acids) and -γενής (-genēs) (producer, literally begetter), is the element with atomic number 8 and represented by the symbol O. It is a member of the chalcogen group on the periodic table, and is a highly (O2) 209,460 ppmv (20.946%)
Argon Argon is a chemical element represented by the symbol Ar. Argon has atomic number 18 and is the third element in group 18 of the periodic table (noble gases). Argon is the third most common gas in the Earth's atmosphere, at 0.93%, making it more common than carbon dioxide. The complete octet (eight electrons) in the outer atomic shell makes it (Ar) 9,340 ppmv (0.9340%)
Carbon dioxide Carbon dioxide is a chemical compound composed of two oxygen atoms covalently bonded to a single carbon atom. It is a gas at standard temperature and pressure and exists in Earth's atmosphere in this state. CO2 is a trace gas comprising 0.039% of the atmosphere (CO2) 390 ppmv (0.039%)
Neon Neon is the chemical element that has the symbol Ne and an atomic number of 10. Although a very common element in the universe, it is rare on Earth. A colorless, inert noble gas under standard conditions, neon gives a distinct reddish-orange glow when used in discharge tubes and neon lamps and advertising signs. It is commercially extracted from (Ne) 18.18 ppmv (0.001818%)
Helium Helium is the chemical element with atomic number 2 and an atomic weight of 4.002602, which is represented by the symbol He. It is a colorless, odorless, tasteless, non-toxic, inert monatomic gas that heads the noble gas group in the periodic table. Its boiling and melting points are the lowest among the elements and it exists only as a gas except (He) 5.24 ppmv (0.000524%)
Methane Methane is a chemical compound with the chemical formula CH4. It is the simplest alkane, and the principal component of natural gas. Methane's bond angles are 109.5 degrees. Burning methane in the presence of oxygen produces carbon dioxide and water. The relative abundance of methane makes it an attractive fuel. However, because it is a gas at (CH4) 1.79 ppmv (0.000179%)
Krypton Krypton is a chemical element with the symbol Kr and atomic number 36. It is a member of Group 18 and Period 4 elements. A colorless, odorless, tasteless noble gas, krypton occurs in trace amounts in the atmosphere, is isolated by fractionally distilling liquified air, and is often used with other rare gases in fluorescent lamps. Krypton is inert (Kr) 1.14 ppmv (0.000114%)
Hydrogen Hydrogen is the chemical element with atomic number 1. It is represented by the symbol H. With an average atomic weight of 1.00794 u (1.007825 u for Hydrogen-1), hydrogen is the lightest and most abundant chemical element, constituting roughly 75 % of the Universe's elemental mass. Stars in the main sequence are mainly composed of hydrogen in its (H2) 0.55 ppmv (0.000055%)
Nitrous oxide Nitrous oxide, commonly known as laughing gas, is a chemical compound with the formula N2O. It is an oxide of nitrogen. At room temperature, it is a colorless non-flammable gas, with a slightly sweet odor and taste. It is used in surgery and dentistry for its anesthetic and analgesic effects. It is known as "laughing gas" due to the (N2O) 0.3 ppmv (0.00003%)
Carbon monoxide Carbon monoxide , also called carbonic oxide, is a colorless, odorless and tasteless gas which is slightly lighter than air. It is highly toxic to humans and animals in higher quantities, although it is also produced in normal animal metabolism in low quantities, and is thought to have some normal biological functions (CO) 0.1 ppmv (0.00001%)
Xenon Xenon is a chemical element represented by the symbol Xe. The element name is pronounced /ˈzɛnɒn/, ZEN-on or /ˈziːnɒn/, ZEE-non. Its atomic number is 54. A colorless, heavy, odorless noble gas, xenon occurs in the Earth's atmosphere in trace amounts. Although generally unreactive, xenon can undergo a few chemical reactions such as the (Xe) 0.09 ppmv (9 × 10−6%)
Ozone Ozone , or trioxygen, is a triatomic molecule, consisting of three oxygen atoms. It is an allotrope of oxygen that is much less stable than the diatomic allotrope (O2). Ozone in the lower atmosphere is an air pollutant with harmful effects on the respiratory systems of animals and will burn sensitive plants; however, the ozone layer in the upper (O3) 0.0 to 0.07 ppmv (0% to 7 × 10−6%)
Nitrogen dioxide (NO2) 0.02 ppmv (2 × 10−6%)
Iodine (I) 0.01 ppmv (1 × 10−6%)
Ammonia (NH3) trace
Not included in above dry atmosphere:
Water vapor (H2O) ~0.40% over full atmosphere, typically 1%-4% at surface

Structure of the atmosphere

Principal layers

Layers of the atmosphere (not to scale)

Earth's atmosphere can be divided into five main layers. These layers are mainly determined by whether temperature increases or decreases with altitude. From highest to lowest, these layers are:

Exosphere
The outermost layer of Earth's atmosphere extends from the exobase upward. Here the particles are so far apart that they can travel hundreds of kilometres without colliding with one another. Since the particles rarely collide, the atmosphere no longer behaves like a fluid. These free-moving particles follow ballistic trajectories and may migrate into and out of the magnetosphere or the solar wind. The exosphere is mainly composed of hydrogen and helium.
Thermosphere
Temperature increases with height in the thermosphere from the mesopause up to the thermopause, then is constant with height. The temperature of this layer can rise to 1,500 °C (2,730 °F), though the gas molecules are so far apart that temperature in the usual sense is not well defined. The International Space Station orbits in this layer, between 320 and 380 km (200 and 240 mi). The top of the thermosphere is the bottom of the exosphere, called the exobase. Its height varies with solar activity and ranges from about 350–800 km (220–500 mi; 1,100,000–2,600,000 ft).
Mesosphere
The mesosphere extends from the stratopause to 80–85 km (50–53 mi; 260,000–280,000 ft). It is the layer where most meteors burn up upon entering the atmosphere. Temperature decreases with height in the mesosphere. The mesopause, the temperature minimum that marks the top of the mesosphere, is the coldest place on Earth and has an average temperature around −85 °C (−121 °F; 188.1 K)[3]. Due to the cold temperature of the mesophere, water vapor is frozen, forming ice clouds (or Noctilucent clouds). A type of lightning referred to as either sprites or ELVES, form many miles above thunderclouds in the trophosphere.
Stratosphere
The stratosphere extends from the tropopause to about 51 km (32 mi; 170,000 ft). Temperature increases with height, which restricts turbulence and mixing. The stratopause, which is the boundary between the stratosphere and mesosphere, typically is at 50 to 55 km (31 to 34 mi; 160,000 to 180,000 ft). The pressure here is 1/1000th sea level.
Troposphere
The troposphere begins at the surface and extends to between 7 km (23,000 ft) at the poles and 17 km (56,000 ft) at the equator, with some variation due to weather. The troposphere is mostly heated by transfer of energy from the surface, so on average the lowest part of the troposphere is warmest and temperature decreases with altitude. This promotes vertical mixing (hence the origin of its name in the Greek word "τροπή", trope, meaning turn or overturn). The troposphere contains roughly 80%[citation needed] of the mass of the atmosphere. The tropopause is the boundary between the troposphere and stratosphere.

Other layers

Within the five principal layers determined by temperature are several layers determined by other properties.

The average temperature of the atmosphere at the surface of Earth is 14 °C (57 °F; 287 K)[5] or 15 °C (59 °F; 288 K)[6], depending on the reference.[7] [8][9]

Physical properties

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